Two-Step Shallow Trench Isolation (STI) Process

ABSTRACT

Methods of making an integrated circuit are disclosed. An embodiment method includes etching a trench in a silicon substrate, depositing a first layer of isolation material in the trench, the first layer of isolation material projecting above surface of the silicon substrate, capping the first layer of isolation material by depositing a second layer of isolation material, the second layer of isolation material extending along at least a portion of sidewalls of the first layer of isolation material, epitaxially-growing a silicon layer upon the silicon substrate, the silicon layer horizontally adjacent to the second layer of isolation material, and forming a gate structure on the silicon layer, the gate structure defining a channel.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation application of U.S. patent application Ser. No. 14/189,879, filed on Feb. 25, 2014, entitled “Two-Step Shallow Trench Isolation (STI) Process,” which application is a divisional of U.S. patent application Ser. No. 13/594,254, filed on Aug. 24, 2012, entitled “Two-Step Shallow Trench Isolation (STI) Process,” which applications are hereby incorporated herein by reference.

BACKGROUND

Semiconductor devices are used in a large number of electronic devices, such as computers, cell phones, and others. Semiconductor devices comprise integrated circuits that are formed on semiconductor wafers by depositing many types of thin films of material over the semiconductor wafers, and patterning the thin films of material to form the integrated circuits. Integrated circuits include field-effect transistors (FETs) such as metal oxide semiconductor (MOS) transistors.

One of the goals of the semiconductor industry is to continue shrinking the size and increasing the speed of individual FETs. However, isolating devices in FETs with sub 65 nm transistor nodes has presented challenges. For example, etching a shallow trench isolation (STI) region trench and filling the STI trench with insulator material becomes more difficult.

One attempt to overcome such challenges involved using tetraethoxysilane (TEOS) as an isolation material. However, use of TEOS may lead to an undesirable humidity absorption concern. In more advanced technology FETs, an oxide is deposited in the STI trench using a high aspect ratio process (HARP) or a Spin-On Glass (SOG) process for device isolation. However, these approaches may require a specific trench profile in order to be successful. For example, an aspect ratio of the STI trench, which is a ratio of the depth to width, may have to be relatively high (e.g., at or above 5). In addition, a slope of the trench may be restricted (e.g., at or below 87 degrees).

In addition to the above, when the STI trench is filled with an insulating material using the HARP process, tensile stress is induced in a channel of the FET and the FET is really only suitable as an NMOS device. On the other hand, when the STI trench is filled using a high density plasma (HDP) process, compressive stress is induced in the channel of the FET and the FET is only really suitable as a PMOS device.

BRIEF DESCRIPTION OF THE DRAWINGS

For a more complete understanding of the present disclosure, and the advantages thereof, reference is now made to the following descriptions taken in conjunction with the accompanying drawing, in which:

FIG. 1 is a cross section of an embodiment FET device having a two-step STI region; and

FIGS. 2-17 collectively illustrate a method of forming the FET device of FIG. 1.

Corresponding numerals and symbols in the different figures generally refer to corresponding parts unless otherwise indicated. The figures are drawn to clearly illustrate the relevant aspects of the embodiments and are not necessarily drawn to scale.

DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS

The making and using of embodiments are discussed in detail below. It should be appreciated, however, that the present disclosure provides many applicable concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed are merely illustrative, and do not limit the scope of the disclosure.

The present disclosure will be described with respect to embodiments in a specific context, namely a field effect transistor (FET) metal oxide semiconductor (MOS). The concept may also be applied, however, to other integrated circuits and electronic structures including.

Referring now to FIG. 1, an embodiment FET device 10 is illustrated. As will be more fully explained below, the FET device 10 includes isolations regions formed using a two-step process. As such, the isolation regions of the FET device 10 are allowed to have a relatively low aspect ratio (e.g., about 3 or less) and are free of restrictive STI trench profile requirements. Moreover, the isolation regions may be formed from high density plasma (HDP) and may employ an N90 or N65 HDP-STI process. Indeed, even a CO11 HDP-STI process may be employed.

Still referring to FIG. 1, the FET device 10 generally includes a substrate 12, a trench 14, a first layer of isolation material 16, a second layer of isolation material 18, an epitaxially-grown silicon layer 20, and a gate structure 22. In an embodiment, the substrate 12 may be formed from a variety of suitable semiconductor materials such as, for example, silicon.

As shown in FIG. 1, the first layer of isolation material 16 occupies or fills the trench 14. In an embodiment, the first layer of isolation material 16 projects above a top surface 24 of the substrate 12. In an embodiment, the first layer of isolation material 16 is a high density plasma (HDP) oxide deposited using a HDP process.

The second layer of isolation material 18 is generally formed over the first layer of isolation material 16. As shown in FIG. 1, the second layer of isolation material 18 is disposed vertically above the first layer of isolation material 16. In an embodiment, the second layer of isolation material 18 caps the first layer of isolation material 16. In other words, the second layer of isolation material 18 encapsulates an upper portion of first layer of isolation material 16. In an embodiment, the second layer of isolation material 18 is a high density plasma (HDP) oxide deposited using a HDP process.

As shown in FIG. 1, the second layer of isolation material 18 may have a bottom surface 26 that abuts or rests upon the top surface 24 of the substrate 12 and a top surface 28 of the first layer of isolation material 16. In addition, a sidewall 30 of the second layer of isolation material 18 may abuts the epitaxially-grown silicon layer 20. In an embodiment, a width 32 of the second layer of isolation material 18 is greater than a width 34 of the first layer of isolation material 16 regardless of where the width of the first layer of isolation material is measured. In others, the width 32 of the second layer of isolation material 18 is greater than the width 34 of the first layer of isolation material 16 at any depth 36 of the first layer of isolation material 16.

The first layer of isolation material 16 and the second layer of isolation material 18 collectively form a two-part isolation structure 38. The two-part isolation structure 38 is generally employed to electrically isolate one FET device 10 from another. Indeed, the two-part isolation structure 38 generally forms, and may be referred to as, a shallow trench isolation (STI) region.

Still referring to FIG. 1, the epitaxially-grown silicon layer 20 is generally grown on the substrate 12. As shown, in an embodiment the epitaxially-grown silicon layer 20 is horizontally adjacent to the second layer of isolation material 18. In an embodiment, the epitaxially-grown silicon layer comprises a silicon germanium (SiGe) or a doped III-V semiconductor material. In an embodiment, the epitaxially-grown silicon layer 20 has a <100> crystal structure, a <110> crystal structure, or a <111> crystal structure. Other semiconductor materials with other crystal structures may also be employed.

In an embodiment, the gate structure 22 (i.e., gate stack) includes, for example, polysilicon layer 40 disposed upon a gate dielectric 42. The gate structure 22 may also be fabricated to include other components such as, for example, spacers, a metal layer, and so on. Such elements have not been expressly depicted in FIG. 1 for ease of illustration.

Referring now to FIGS. 2-17, an embodiment method of forming the FET device 10 of FIG. 1 is collectively illustrated. With regard to FIG. 2, the method commences with a cleaning of the silicon substrate 12. Thereafter, as shown in FIG. 3, a nitride layer 44 is deposited on the silicon substrate 12. As shown in FIG. 4, a photoresist 46 is disposed upon portions of the nitride layer 44 to define a pattern for a shallow trench isolation (STI) etch.

Referring now to FIGS. 4-5, an etching process is performed to remove select portions of the nitride layer 44 and the silicon substrate 12 not protected by the photoresist 46, which produces the trench 14. In an embodiment, the trench 14 has an aspect ratio of below about 3. Moving to FIG. 6, the trench 14 is filled with the first layer of isolation material 16 (e.g., an HDP Oxide deposited through a HDP Oxide deposition process). Thereafter, as shown in FIG. 7, a Chemical-Mechanical Planarization (CMP) process is performed to remove a portion of the first layer of isolation material 16. Indeed, as shown in FIG. 7, after the CMP process the first layer of isolation material 16 occupying the trench 14 and the nitride layer 44 are generally co-planar.

Referring now to FIGS. 7-8, the nitride layer 44 is removed. As shown, removal of the nitride layer 44 causes the first layer of isolation material 16 to project above the top surface 24 of the silicon substrate 12. Next, as shown in FIG. 9, the second layer of isolation material 18 (e.g., an HDP Oxide deposited through a HDP Oxide deposition process) is blanket deposited over the first layer of isolation material 16 and the silicon substrate 12. Thereafter, as shown in FIG. 10, an additional nitride layer 44 is formed over the second layer of isolation material 18.

As shown in FIG. 11 another photoresist 46 is disposed upon the additional nitride layer 44 to define a pattern for formation of the two-part STI structure 38 (FIG. 1). Referring now to FIGS. 11-12, an etching process is performed to remove portions of the nitride layer 44 and the second layer of isolation material 18 not protected by the photoresist 46 to define the two-part STI structure 38 beneath the remaining portions of the additional nitride layer 44.

Moving now to FIG. 13, the silicon layer 20 is epitaxially grown on the silicon substrate 12 between adjacent two-part STI structures 38. Thereafter, as shown in FIG. 14, another CMP process is performed to remove a portion of the epitaxially-grown silicon layer 20 as well as the nitride layer 44 remaining over first layer of isolation material 16. As shown in FIG. 14, after the CMP process the epitaxially-grown silicon layer 20 and the second layer of isolation material 18 are generally co-planar. Thereafter, a hydrogen anneal process is performed to repair and relax the epitaxially-grown silicon layer 20. As noted above, the epitaxially-grown silicon layer 20 may be afforded a <100> crystal structure, a <110> crystal structure, or a <111> crystal structure, depending on the performance characteristics desired for the FET device 10 (FIG. 1).

Referring now to FIG. 15, a gate material cleaning and deposition process is performed. As shown, the gate dielectric 42 and polysilicon layer 40, among other components, may be formed over the two-part STI structure 38 during this process. Thereafter, as shown in FIG. 16, another photoresist 46 is disposed upon the polysilicon layer 40 to define a pattern for formation of the gate structure 22 (FIG. 1). Referring now to FIGS. 16-17, an etching process is performed to remove portions of the polysilicon layer 40 and the gate dielectric 42 not protected by the photoresist 46 to define the gate structure 22 above the epitaxially-grown silicon layer 20 and form the FET device 10 of FIG. 1. It should be recognized that further or additional fabrication or manufacturing steps or processes may be performed to form or augment the FET device 10 of FIG. 1. However, for the sake of brevity such additional steps or processes have been omitted.

The FET device 10 of FIGS. 1 and 17 has several advantages relative to conventional or known FET devices. For example, the FET device 10 mitigates or eliminates STI trench etch and insulator material gap-filling difficulties. The FET device 10 may also include an STI region formed using HDP Oxide and an HDP Oxide process in sub 40 nm nodes.

In addition to the above, the FET device 10 has a lower aspect ratio (e.g., about 3) relative to conventional FET devices that mandate a higher aspect ratio (e.g., about 5). Moreover, the FET device 10 is not limited to conventional STI trench profile requirements. In addition, the FET device 10 generates less stress in a channel 48 disposed beneath the gate structure 22 (FIG. 17), which makes the FET device 10 suitable for both PMOS and NMOS applications. Indeed, the FET device 10 avoids the STI stress impact to the channel 48 and induced drain saturation current (I_(dsat)) performance loss.

In an embodiment, a method of forming an integrated circuit device includes etching a trench in a silicon substrate, depositing a first layer of isolation material in the trench, the first layer of isolation material projecting above surface of the silicon substrate, capping the first layer of isolation material by depositing a second layer of isolation material, the second layer of isolation material extending along at least a portion of sidewalls of the first layer of isolation material, epitaxially-growing a silicon layer upon the silicon substrate, the silicon layer horizontally adjacent to the second layer of isolation material, and forming a gate structure on the silicon layer, the gate structure defining a channel.

In an embodiment, a method of forming an integrated circuit device includes forming a trench in a silicon substrate, forming a two-part isolation structure over the silicon substrate, the two part isolation structure including a first oxide layer and a second oxide layer, the first oxide layer filling the trench and projecting above the silicon substrate, the second oxide layer capping the first oxide layer such that the second oxide layer abuts at least a portion of sidewalls of the first oxide layer, epitaxially-growing a silicon layer on the silicon substrate, the silicon layer horizontally adjacent to the two-part isolation structure, and forming a gate structure on the silicon layer, the gate structure defining a channel.

In an embodiment, a method of forming an integrated circuit device includes etching a first trench and a second trench in a silicon substrate, forming a first two-part isolation structure within and over the first trench and a second two-part isolation structure within and over the second trench, each of the first and second two part isolation structures including a first oxide layer and a second oxide layer, the first oxide layer filling the first and second trenches and projecting above the silicon substrate, the second oxide layer capping the first oxide layer such that the second oxide layer abuts at least a portion of sidewalls of the first oxide layer, epitaxially-growing a silicon layer between the second oxide layer of the first and second two-part isolation structures, and forming a gate structure on the silicon layer between the first and second two-part isolation structures.

In another embodiment, a method of forming an integrated circuit device is provided. The method includes forming a patterned mask having openings on a substrate, and forming trenches in the substrate in the openings of the patterned mask. A first isolation material is formed in the trenches. The patterned mask is removed and a second isolation material is formed over the first isolation material. After forming the second isolation material, a semiconductor device is formed between the second isolation material over adjacent trenches.

In yet still another embodiment, a method of forming an integrated circuit device is provided. The method includes forming a patterned mask on a substrate, the patterned mask having a first opening and a second opening, and forming a first trench in the substrate in the first opening and a second trench in the substrate in the second opening. A first isolation material is formed in the first trench and the second trench. The patterned mask is removed and a second isolation material is formed over the first isolation material in the first trench and the first isolation material in the second trench. The second isolation material is patterned to expose at least a portion of the substrate between the first trench and the second trench. A semiconductor device is formed between the second isolation material over the first trench and the second isolation material over the second trench.

In yet still another embodiment, a method of forming an integrated circuit device is provided. The method includes forming a first trench in a substrate having a mask layer thereon, and forming a first isolation material in the first trench. At least a portion of the mask layer is removed, and a second isolation material is formed over the first isolation material, the substrate being exposed adjacent to the second isolation material. An epitaxial material is epitaxially grown on the substrate adjacent the second isolation material.

While the disclosure provides illustrative embodiments, this description is not intended to be construed in a limiting sense. Various modifications and combinations of the illustrative embodiments, as well as other embodiments, will be apparent to persons skilled in the art upon reference to the description. It is therefore intended that the appended claims encompass any such modifications or embodiments. 

What is claimed is:
 1. A method of forming an integrated circuit device, the method comprising: forming a patterned mask on a substrate, the patterned mask having openings; forming trenches in the substrate in the openings of the patterned mask; forming a first isolation material in the trenches; removing the patterned mask; forming a second isolation material over the first isolation material; and after forming the second isolation material, forming a semiconductor device between the second isolation material over adjacent trenches.
 2. The method of claim 1, wherein the first isolation material extends above an uppermost surface of the substrate.
 3. The method of claim 2, wherein the second isolation material extends along sidewalls of the first isolation material.
 4. The method of claim 1, further comprising epitaxially growing a semiconductor material between the second isolation material extending above adjacent trenches, wherein the forming the semiconductor device comprises forming the semiconductor device on the semiconductor material.
 5. The method of claim 4, wherein the semiconductor material has a <100> crystal structure, a <110> crystal structure, or a <111> crystal structure.
 6. The method of claim 1, further comprising, after forming the first isolation material, planarizing the first isolation material such that the first isolation material and the patterned mask are co-planar.
 7. A method of forming an integrated circuit device, the method comprising: forming a patterned mask on a substrate, the patterned mask having a first opening and a second opening; forming a first trench in the substrate in the first opening and a second trench in the substrate in the second opening; forming a first isolation material in the first trench and the second trench; removing the patterned mask; forming a second isolation material over the first isolation material in the first trench and the first isolation material in the second trench; patterning the second isolation material to expose at least a portion of the substrate between the first trench and the second trench; and forming a semiconductor device between the second isolation material over the first trench and the second isolation material over the second trench.
 8. The method of claim 7, wherein the first isolation material extends above an uppermost surface of the substrate.
 9. The method of claim 8, wherein the second isolation material extends along sidewalls of the first isolation material.
 10. The method of claim 7, wherein forming the semiconductor device comprises epitaxially growing an epitaxial material on the substrate.
 11. The method of claim 10, wherein the epitaxial material extends to an upper surface of the second isolation material.
 12. The method of claim 10, further comprising planarizing the epitaxial material such that a surface of the epitaxial material is coplanar with a surface of the second isolation material.
 13. The method of claim 10, wherein the epitaxial material has a <100> crystal structure, a <110> crystal structure, or a <111> crystal structure.
 14. A method of forming an integrated circuit device, the method comprising: forming a first trench in a substrate, the substrate having a mask layer thereon; forming a first isolation material in the first trench; removing at least a portion of the mask layer; forming a second isolation material over the first isolation material, the substrate being exposed adjacent to the second isolation material; and epitaxially growing an epitaxial material on the substrate adjacent the second isolation material.
 15. The method of claim 14, wherein the forming the first isolation material comprises using a high density oxide deposition process.
 16. The method of claim 14, wherein the epitaxial material comprises a doped III-V semiconductor material.
 17. The method of claim 14, further comprising planarizing the first isolation material such that an upper surface of the first isolation material is coplanar with an upper surface of the mask layer.
 18. The method of claim 17, further comprising planarizing the epitaxial material such that an upper surface of the epitaxial material is coplanar with an upper surface of the second isolation material.
 19. The method of claim 14, wherein the second isolation material extends along sidewalls of the first isolation material.
 20. The method of claim 14, wherein the forming the second isolation material comprises forming a layer of the second isolation material and patterning the layer of the second isolation material to expose an upper surface of the substrate. 